{"id":8390,"date":"2026-10-23T10:13:49","date_gmt":"2026-10-23T01:13:49","guid":{"rendered":"https:\/\/tuat-chemphys.net\/?p=8390"},"modified":"2026-10-23T10:26:40","modified_gmt":"2026-10-23T01:26:40","slug":"phd-presentation-%e5%85%ac%e8%81%b4%e4%bc%9a-10-23-catalysts-for-steam-reforming-of-bio-oil-derived%ef%bc%88%e3%83%90%e3%82%a4%e3%82%aa%e3%83%9e%e3%82%b9%e7%94%b1%e6%9d%a5%e3%83%90%e3%82%a4%e3%82%aa","status":"publish","type":"post","link":"https:\/\/tuat-chemphys.net\/?p=8390","title":{"rendered":"PhD Presentation \u516c\u8074\u4f1a (10\/23) Catalysts for Steam Reforming of Bio-oil Derived\uff08\u30d0\u30a4\u30aa\u30de\u30b9\u7531\u6765\u30d0\u30a4\u30aa\u30aa\u30a4\u30eb\u306e\u6c34\u84b8\u6c17\u6539\u8cea\u306e\u305f\u3081\u306e\u89e6\u5a92\uff09"},"content":{"rendered":"\n<p class=\"wp-block-paragraph\">\u65e5\u6642\uff1a10\u670823\u65e5\uff08\u6c34\uff0916\uff1a30\uff5e18:00 <\/p>\n\n\n\n<p class=\"wp-block-paragraph\">\u5834\u6240\uff1aBASE\u68df\u8b1b\u7fa9\u5ba4\uff14\uff08\uff11F\u3001\u65e7\u4f1a\u8b70\u5ba4\uff09 <\/p>\n\n\n\n<p class=\"wp-block-paragraph\">\u8ad6\u6587\u984c\u76ee\uff1aDesign of Encapsulated Ni-Based Catalysts for Steam Reforming of Bio-oil Derived \uff08\u30d0\u30a4\u30aa\u30de\u30b9\u7531\u6765\u30d0\u30a4\u30aa\u30aa\u30a4\u30eb\u306e\u6c34\u84b8\u6c17\u6539\u8cea\u306e\u305f\u3081\u306e\u5185\u5305\u578bNi\u7cfb\u89e6\u5a92\u306e\u8a2d\u8a08\uff09<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">PhD candidate:  S. Silmina<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Meeting<br><a href=\"https:\/\/tuat-jp.zoom.us\/j\/82213909799?pwd=cxelxrIpQHrvAF0adWbfzn3rTWTif7.1\">https:\/\/tuat-jp.zoom.us\/j\/82213909799?pwd=cxelxrIpQHrvAF0adWbfzn3rTWTif7.1<\/a><br>Meeting ID: 822 1390 9799<br>Passcode: 664417<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">A reference:<\/p>\n\n\n\n<p class=\"wp-block-paragraph\"><a href=\"https:\/\/doi.org\/10.1016\/j.fuel.2026.141463\">https:\/\/doi.org\/10.1016\/j.fuel.2026.141463<\/a><br>Steam reforming of acetic acid over Ni nanoparticle catalysts encapsulated on Al2O3 using cellulose nanofibers (CNFs) as a template: the role of promoter addition<\/p>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"486\" height=\"200\" data-attachment-id=\"8393\" data-permalink=\"https:\/\/tuat-chemphys.net\/?attachment_id=8393\" data-orig-file=\"https:\/\/tuat-chemphys.net\/wp-content\/uploads\/2026\/10\/image.png\" data-orig-size=\"486,200\" data-comments-opened=\"0\" data-image-title=\"image\" data-image-description=\"\" data-image-caption=\"\" data-large-file=\"https:\/\/tuat-chemphys.net\/wp-content\/uploads\/2026\/10\/image.png\" src=\"https:\/\/tuat-chemphys.net\/wp-content\/uploads\/2026\/10\/image.png\" alt=\"\" class=\"wp-image-8393\" srcset=\"https:\/\/tuat-chemphys.net\/wp-content\/uploads\/2026\/10\/image.png 486w, https:\/\/tuat-chemphys.net\/wp-content\/uploads\/2026\/10\/image-300x123.png 300w\" sizes=\"auto, (max-width: 486px) 100vw, 486px\" \/><\/figure>\n\n\n\n<h2 class=\"wp-block-heading\">Highlights:<\/h2>\n\n\n\n<ul class=\"wp-block-list\">\n<li>New design of Ni catalysts was encapsulated on Al<sub>2<\/sub>O<sub>3<\/sub> using CNFs as template.<\/li>\n\n\n\n<li>CNFs addition strongly influenced catalytic steam reforming performance.<\/li>\n\n\n\n<li>ZrO<sub>2<\/sub>, MgO, and CeO<sub>2<\/sub> significantly increased H<sub>2<\/sub> yield with each playing a different role.<\/li>\n\n\n\n<li>Promoted CNFs-templated Ni NPs catalysts showed improved stability, resisting carbon deposition and sintering.<\/li>\n<\/ul>\n\n\n\n<h2 class=\"wp-block-heading\">Abstract<\/h2>\n\n\n\n<p class=\"wp-block-paragraph\">A novel cellulose nanofiber (CNFs)-templated Ni-Al<sub>2<\/sub>O<sub>3<\/sub> catalyst was developed to enable efficient steam reforming of bio-oil aqueous-phase components. CNFs derived from sustainable pulp feedstock served as sacrificial structural templates, promoting hierarchical porosity and improving the dispersion of nickel (Ni) nanoparticles (NPs). Optimization of CNFs template addition demonstrated that Ni\u00a9<sub>0.2<\/sub>Al<sub>2<\/sub>O<sub>3<\/sub> (0.2&nbsp;g) achieved complete acetic acid conversion and a 78.3% H<sub>2<\/sub> yield at 650&nbsp;\u00b0C and 0.1&nbsp;MPa, surpassing both lower (0.1&nbsp;g) and higher (0.3&nbsp;g) CNFs additions. The incorporation of metal oxide promoters (CeO<sub>2<\/sub>, MgO, ZrO<sub>2<\/sub>) into the optimal Ni\u00a9<sub>0.2<\/sub>Al<sub>2<\/sub>O<sub>3<\/sub> catalyst further increased H<sub>2<\/sub> yield: Ni\u00a9<sub>0.2<\/sub>Ce-Al<sub>2<\/sub>O<sub>3<\/sub> reached 91.0% due to redox-driven oxygen mobility, Ni\u00a9<sub>0.2<\/sub>Mg-Al<sub>2<\/sub>O<sub>3<\/sub> achieved 89.1% as a result of enhanced basicity, and Ni\u00a9<sub>0.2<\/sub>Zr-Al<sub>2<\/sub>O<sub>3<\/sub> attained 89.7% owing to strengthened metal-support interactions. The promoted catalysts maintained complete acetic acid conversion during a 24-hour durability test, with significant carbon balance closure, indicating stable catalytic performance. This enhanced durability is attributed to the selective redirection of carbon deposition toward non-poisoning, support-localized C<sub>\u03b2<\/sub> species (graphitic or filamentous carbon) rather than active-site-blocking C<sub>\u03b1<\/sub> (amorphous carbon).<\/p>\n","protected":false},"excerpt":{"rendered":"<p> \u8ad6\u6587\u984c\u76ee\uff1aDesign of Encapsulated Ni-Based Catalysts for Steam Reforming of Bio-oil Derived \uff08\u30d0\u30a4\u30aa\u30de\u30b9\u7531\u6765\u30d0\u30a4\u30aa\u30aa\u30a4\u30eb\u306e\u6c34\u84b8\u6c17\u6539\u8cea\u306e\u305f\u3081\u306e\u5185\u5305\u578bNi\u7cfb\u89e6\u5a92\u306e\u8a2d\u8a08\uff09<\/p>\n","protected":false},"author":1,"featured_media":8393,"comment_status":"closed","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"advanced_seo_description":"","jetpack_seo_html_title":"","jetpack_seo_noindex":false,"jetpack_seo_schema_type":"","_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_feature_clip_id":0,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2},"jetpack_post_was_ever_published":false},"categories":[22],"tags":[12,14,15],"class_list":["post-8390","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-doctoral-thesis-","tag-energy-conversion-optimization","tag-advanced-materials-creation","tag-environmental-technology"],"jetpack_publicize_connections":[],"jetpack_sharing_enabled":true,"jetpack-related-posts":[{"id":7198,"url":"https:\/\/tuat-chemphys.net\/?p=7198","url_meta":{"origin":8390,"position":0},"title":"\u535a\u58eb\u516c\u8074\u4f1a 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\u535a\u58eb\u8ad6\u6587","link":"https:\/\/tuat-chemphys.net\/?cat=22"},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/01\/image-6.png?resize=350%2C200&ssl=1","width":350,"height":200},"classes":[]},{"id":7949,"url":"https:\/\/tuat-chemphys.net\/?p=7949","url_meta":{"origin":8390,"position":1},"title":"Guest Seminar (6\/2) Advanced Catalyst Technologies for Sustainable Bio-Oil Processing\/ \u6301\u7d9a\u53ef\u80fd\u306a\u30d0\u30a4\u30aa\u6cb9\u51e6\u7406\u306e\u305f\u3081\u306e\u5148\u9032\u89e6\u5a92\u6280\u8853","author":"unet","date":"2026-05","format":false,"excerpt":"\u984c\u76ee:\u00a0Rational\u00a0Catalyst\u00a0Design\u00a0for\u00a0Hydrogen-Efficient\u00a0and\u00a0Scalable\u00a0Bio-Oil\u00a0Upgrading (\u6c34\u7d20\u52b9\u7387\u578b\u304a\u3088\u3073\u00a0\u30b9\u30b1\u30fc\u30e9\u30d6\u30eb\u306a\u30d0\u30a4\u30aa\u6cb9\u306e\u9ad8\u5ea6\u5316\u306e\u305f\u3081\u306e\u5408\u7406\u7684\u89e6\u5a92\u8a2d\u8a08)","rel":"","context":"In &quot;Guest Seminar&quot;","block_context":{"text":"Guest Seminar","link":"https:\/\/tuat-chemphys.net\/?cat=8"},"img":{"alt_text":"erlenmeyer flask with colored liquid inside","src":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/05\/pexels-photo-6608506.jpeg?resize=350%2C200&ssl=1","width":350,"height":200,"srcset":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/05\/pexels-photo-6608506.jpeg?resize=350%2C200&ssl=1 1x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/05\/pexels-photo-6608506.jpeg?resize=525%2C300&ssl=1 1.5x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/05\/pexels-photo-6608506.jpeg?resize=700%2C400&ssl=1 2x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/05\/pexels-photo-6608506.jpeg?resize=1050%2C600&ssl=1 3x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/05\/pexels-photo-6608506.jpeg?resize=1400%2C800&ssl=1 4x"},"classes":[]},{"id":7208,"url":"https:\/\/tuat-chemphys.net\/?p=7208","url_meta":{"origin":8390,"position":2},"title":"PhD Thesis \u516c\u8074\u4f1a Carbon-Based Solid Acid Catalysts for Biomass \u30ea\u30b0\u30ce\u30bb\u30eb\u30ed\u30fc\u30b9\u7cfb\u30d0\u30a4\u30aa\u30de\u30b9\u306e\u7cd6\u5316 (Jan.28, 14:30)","author":"unet","date":"2026-01","format":false,"excerpt":"Thesis Title: \u201cSaccharification of Lignocellulosic Biomass by Using Biomass-derived Carbon-based Solid Acid Catalysts\u201d","rel":"","context":"In &quot;Doctoral Thesis \u535a\u58eb\u8ad6\u6587&quot;","block_context":{"text":"Doctoral Thesis 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\u535a\u58eb\u516c\u8074\u4f1a\uff1a\u30d0\u30a4\u30aa\u30de\u30b9\u7531\u6765\u6eb6\u5a92\u3092\u7528\u3044\u305f\u03b3-\u30d6\u30c1\u30ed\u30e9\u30af\u30c8\u30f3\u751f\u6210 (5\/11) Doctoral Public Hearing by Nanami Hirano Production of \u03b3-Butyrolactone Using a Biomass-Derivable Solvent","author":"unet","date":"2026-05","format":false,"excerpt":"Production of \u03b3-Butyrolactone from Succinic Acid Using Biomass-derivable Tetrahydrofuran Solvent (\u30d0\u30a4\u30aa\u30de\u30b9\u304b\u3089\u88fd\u9020\u53ef\u80fd\u306a\u30c6\u30c8\u30e9\u30d2\u30c9\u30ed\u30d5\u30e9\u30f3\u6eb6\u5a92\u3092\u7528\u3044\u305f\u30b3\u30cf\u30af\u9178\u304b\u3089\u306e\u03b3-\u30d6\u30c1\u30ed\u30e9\u30af\u30c8\u30f3\u751f\u6210)","rel":"","context":"In &quot;Doctoral Thesis \u535a\u58eb\u8ad6\u6587&quot;","block_context":{"text":"Doctoral Thesis \u535a\u58eb\u8ad6\u6587","link":"https:\/\/tuat-chemphys.net\/?cat=22"},"img":{"alt_text":"PhD thesis by Hawking's student Simon Ross, titled: Black hole 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students","author":"unet","date":"2021-12","format":false,"excerpt":"\u92ad \u6559\u6388\u306e\u30a4\u30f3\u30bf\u30d3\u30e5\u30fc\u8a18\u4e8b\u30021\u3064\u306e\u89e6\u5a92\u3067\u30d0\u30a4\u30aa\u30de\u30b9\u3092\u822a\u7a7a\u6a5f\u30b8\u30a7\u30c3\u30c8\u71c3\u6599\u306b\u5909\u63db\u3059\u308b\u9769\u65b0\u7684\u6280\u8853\u306e\u958b\u767a\u3084\u3001\u6301\u7d9a\u53ef\u80fd\u306a\u793e\u4f1a\u3092\u76ee\u6307\u3059\u92ad\u7814\u7a76\u5ba4\u306e\u5b66\u751f\u305f\u3061\u306e\u7814\u7a76\u6210\u679c\u3092\u7d39\u4ecb\u3057\u307e\u3059\u3002 \/ Interview feature on Prof. Qian. Introducing breakthrough catalyst design technology for converting biomass into sustainable aviation fuel (SAF) and the research activities of students in the Qian Lab.","rel":"","context":"In &quot;Professor's Interview&quot;","block_context":{"text":"Professor's Interview","link":"https:\/\/tuat-chemphys.net\/?cat=5"},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/09\/image-3.png?resize=350%2C200&ssl=1","width":350,"height":200,"srcset":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/09\/image-3.png?resize=350%2C200&ssl=1 1x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/09\/image-3.png?resize=525%2C300&ssl=1 1.5x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/09\/image-3.png?resize=700%2C400&ssl=1 2x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/09\/image-3.png?resize=1050%2C600&ssl=1 3x"},"classes":[]},{"id":8149,"url":"https:\/\/tuat-chemphys.net\/?p=8149","url_meta":{"origin":8390,"position":5},"title":"\u3010\u535a\u58eb\u8ad6\u6587\u516c\u8074\u4f1a \/ PhD Thesis\u3011CO2\u3092\u5316\u5b66\u7269\u8cea\u3078\u5909\u63db\u3059\u308b\u89e6\u5a92\u7814\u7a76 Catalytic Conversion of CO2 into Chemicals (8\/19)","author":"unet","date":"2026-08","format":false,"excerpt":"\u6e29\u5ba4\u52b9\u679c\u30ac\u30b9\u3067\u3042\u308b\u4e8c\u9178\u5316\u70ad\u7d20\uff08CO2\uff09\u3092\u6709\u7528\u306a\u5316\u6210\u54c1\u3078\u9ad8\u52b9\u7387\u306b\u5909\u63db\u3059\u308b\u89e6\u5a92\u958b\u767a\u3068\u3001\u305d\u306e\u53cd\u5fdc\u6a5f\u69cb\u306e\u89e3\u660e\u306b\u95a2\u3059\u308b\u7814\u7a76Research on developing high-performance catalysts to convert CO2 into valuable chemicals and elucidating their reaction mechanisms.","rel":"","context":"In &quot;Doctoral Thesis \u535a\u58eb\u8ad6\u6587&quot;","block_context":{"text":"Doctoral Thesis \u535a\u58eb\u8ad6\u6587","link":"https:\/\/tuat-chemphys.net\/?cat=22"},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/08\/image-2.png?resize=350%2C200&ssl=1","width":350,"height":200,"srcset":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/08\/image-2.png?resize=350%2C200&ssl=1 1x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/08\/image-2.png?resize=525%2C300&ssl=1 1.5x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/08\/image-2.png?resize=700%2C400&ssl=1 2x"},"classes":[]}],"jetpack_shortlink":"https:\/\/wp.me\/pa3J4g-2bk","jetpack_likes_enabled":true,"jetpack_featured_media_url":"https:\/\/tuat-chemphys.net\/wp-content\/uploads\/2026\/10\/image.png","_links":{"self":[{"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/posts\/8390","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=8390"}],"version-history":[{"count":3,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/posts\/8390\/revisions"}],"predecessor-version":[{"id":8394,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/posts\/8390\/revisions\/8394"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/media\/8393"}],"wp:attachment":[{"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=8390"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=8390"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=8390"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}