{"id":8343,"date":"2026-10-02T10:50:31","date_gmt":"2026-10-02T01:50:31","guid":{"rendered":"https:\/\/tuat-chemphys.net\/?p=8343"},"modified":"2026-10-04T10:39:35","modified_gmt":"2026-10-04T01:39:35","slug":"%e3%81%a9%e3%81%a3%e3%81%a1%e3%82%92%e5%90%91%e3%81%91%e3%81%b0%e3%81%84%e3%81%84%e3%81%ae%ef%bc%9f%e5%8e%9f%e5%ad%90%e3%81%ae%e7%a3%81%e7%9f%b3%e3%81%8c%e8%bf%b7%e3%81%84%e7%b6%9a%e3%81%91%e3%82%8b","status":"publish","type":"post","link":"https:\/\/tuat-chemphys.net\/?p=8343","title":{"rendered":"\u3069\u3063\u3061\u3092\u5411\u3051\u3070\u3044\u3044\u306e\uff1f\u539f\u5b50\u306e\u78c1\u77f3\u304c\u8ff7\u3044\u7d9a\u3051\u308b\u4e0d\u601d\u8b70\u306a\u7d50\u6676”Which way should I point?” A strange crystal where atomic magnets"},"content":{"rendered":"\n

🧲\u3053\u306e\u7814\u7a76\u306e\u30dd\u30a4\u30f3\u30c8\u30003\u3064\u306e\u8981\u70b9<\/strong><\/p>\n\n\n\n

\n

✅\u4f55\u3092\u8abf\u3079\u305f\u304b\uff1f<\/strong>
\u78c1\u77f3\u306e\u5411\u304d\u304c\u304a\u4e92\u3044\u306b\u90aa\u9b54\u3057\u5408\u3063\u3066\u6c7a\u3081\u3089\u308c\u306a\u304f\u306a\u308b\u3001\u30b8\u30e3\u30f3\u30b0\u30eb\u30b8\u30e0\u306e\u3088\u3046\u306a\u7acb\u4f53\u69cb\u9020\uff08\u30c8\u30ea\u30ea\u30a6\u30e0\u683c\u5b50\uff09\u3092\u6301\u3064\u65b0\u3057\u3044\u9178\u5316\u7269\uff08Li\u2082NiGe\u2083O\u2088<\/strong>\uff09\u3092\u5408\u6210\u3057\u3066\u8abf\u3079\u307e\u3057\u305f\u3002<\/p>\n\n\n\n

✅\u4f55\u304c\u308f\u304b\u3063\u305f\u306e\u304b\uff1f<\/strong>
\u6e29\u5ea6\u3092\u4e0b\u3052\u3066\u3082\u78c1\u77f3\u306e\u5411\u304d\u304c\u4e00\u6589\u306b\u63c3\u3063\u3066\u30ab\u30c1\u30c3\u3068\u56fa\u307e\u308b\u306e\u3067\u306f\u306a\u304f\u3001\u5e83\u3044\u6e29\u5ea6\u7bc4\u56f2\u3067\u304a\u4e92\u3044\u306e\u5411\u304d\u3092\u6c17\u306b\u3057\u306a\u304c\u3089\u3058\u308f\u3058\u308f\u3068\u72b6\u614b\u304c\u5909\u5316\u3057\u3066\u3044\u304f\u4e0d\u601d\u8b70\u306a\u69d8\u5b50\uff08\u78c1\u6c17\u7684\u76f8\u95a2<\/strong>\uff09\u304c\u78ba\u8a8d\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n\n\n\n

✅\u3069\u3046\u3057\u3066\u5927\u5207\u306a\u306e\u304b\uff1f<\/strong>
\u3053\u308c\u307e\u3067\u7406\u8ad6\uff08\u8a08\u7b97\uff09\u306e\u4e2d\u3067\u8003\u3048\u3089\u308c\u3066\u3044\u305f\u8907\u96d1\u306a\u78c1\u77f3\u306e\u30e2\u30c7\u30eb\u3068\u3001\u5b9f\u969b\u306e\u7269\u8cea\u306e\u6027\u8cea\u3092\u6bd4\u8f03\u3057\u3066\u691c\u8a3c\u3067\u304d\u308b\u8cb4\u91cd\u306a\u6750\u6599\uff08\u9178\u5316\u7269\uff09\u306b\u306a\u308b\u3053\u3068\u304c\u793a\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n<\/div><\/div>\n\n\n\n

🧲1.<\/strong> \u80cc\u666f<\/strong><\/p>\n\n\n\n

N\u6975\u3068S\u6975\u3092\u6301\u3064\u5c0f\u3055\u306a\u300c\u539f\u5b50\u306e\u78c1\u77f3\u300d\u304c\u96c6\u307e\u308b\u3068\u3001\u3075\u3064\u3046\u306f\u6e29\u5ea6\u3092\u4e0b\u3052\u305f\u3068\u304d\u306b\u5168\u54e1\u304c\u30eb\u30fc\u30eb\u306b\u5f93\u3063\u3066\u304d\u308c\u3044\u306b\u4e26\u3073\u307e\u3059\u304c\u3001\u539f\u5b50\u306e\u914d\u7f6e\u306b\u3088\u3063\u3066\u306f\u300c\u96a3\u306e\u78c1\u77f3\u3068\u3069\u3063\u3061\u3092\u5411\u3051\u3070\u3044\u3044\u306e\u304b\u6c7a\u3081\u3089\u308c\u306a\u3044\u300d\u3068\u3044\u3046\u56f0\u3063\u305f\u72b6\u614b\uff08\u7269\u7406\u5b66\u3067\u300c\u30d5\u30e9\u30b9\u30c8\u30ec\u30fc\u30b7\u30e7\u30f3\uff08\u845b\u85e4\uff09\u300d\u3068\u547c\u3073\u307e\u3059\uff09\u304c\u8d77\u3053\u308a\u307e\u3059\u3002\u3053\u306e\u3088\u3046\u306a\u73fe\u8c61\u304c\u8d77\u304d\u308b\u73cd\u3057\u3044\u7acb\u4f53\u69cb\u9020\u300c\u30c8\u30ea\u30ea\u30a6\u30e0\u683c\u5b50\u300d\u306f\u3001\u3053\u308c\u307e\u3067\u4e3b\u306b\u91d1\u5c5e\u3067\u7814\u7a76\u3055\u308c\u3066\u304d\u307e\u3057\u305f\u3002<\/p>\n\n\n\n

\u3057\u304b\u3057\u3001\u96fb\u6c17\u3092\u901a\u3055\u306a\u3044\u300c\u9178\u5316\u7269\uff08\u30bb\u30e9\u30df\u30c3\u30af\u30b9\u306e\u3088\u3046\u306a\u6750\u6599\uff09\u300d\u3067\u8abf\u3079\u308b\u3053\u3068\u3067\u3001\u3088\u308a\u30b7\u30f3\u30d7\u30eb\u306b\u78c1\u77f3\u306e\u6027\u8cea\u3092\u7406\u8ad6\u3084\u8a08\u7b97\u30e2\u30c7\u30eb\u3068\u6bd4\u8f03\u3067\u304d\u308b\u3088\u3046\u306b\u306a\u308b\u3068\u671f\u5f85\u3055\u308c\u3066\u3044\u307e\u3057\u305f\u3002<\/p>\n\n\n\n

<\/p>\n\n\n\n

🧲2.<\/strong> \u8abf\u3079\u305f\u3053\u3068\u3068\u7d50\u679c<\/strong><\/p>\n\n\n\n

\u672c\u7814\u7a76\u3067\u306f\u3001\u30cb\u30c3\u30b1\u30eb\uff08Ni\uff09\u3092\u542b\u3080\u65b0\u3057\u3044\u9178\u5316\u7269\uff08Li\u2082NiGe\u2083O\u2088\uff09<\/strong>\u306e\u7c89\u672b\u3092\u4f5c\u308a\u3001\u305d\u306e\u7d50\u6676\u69cb\u9020\u3084\u78c1\u6c17\u306e\u6027\u8cea\u3092\u6e2c\u5b9a\u3057\u307e\u3057\u305f\u3002<\/p>\n\n\n\n

\u3000🔳\u5f62\u306e\u78ba\u8a8d<\/strong>\uff1a X\u7dda\u3092\u4f7f\u3063\u305f\u6e2c\u5b9a\u306b\u3088\u308a\u3001\u30cb\u30c3\u30b1\u30eb\u539f\u5b50\u304c\u304d\u308c\u3044\u306a\u300c\u30c8\u30ea\u30ea\u30a6\u30e0\u683c\u5b50\u300d\u306e\u5f62\u306b\u4e26\u3093\u3067\u3044\u308b\u3053\u3068\u304c\u78ba\u8a8d\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n\n\n\n

\u3000🔳\u78c1\u5316\u7387\u306e\u6e2c\u5b9a\uff1a<\/strong> \u3000\u6e29\u5ea6\u3092\u7d04 -263 \u2103\uff0810 K\uff09\u8fd1\u304f\u307e\u3067\u4e0b\u3052\u3066\u3044\u304f\u3068\u3001\u5e73\u5747\u7684\u306a\u78c1\u5834\u306f\u30bc\u30ed\u306b\u8fd1\u304f\u3066\u3082\u3001\u78c1\u77f3\u3069\u3046\u3057\u304c\u304a\u4e92\u3044\u306e\u5411\u304d\u3092\u3086\u3063\u304f\u308a\u6c17\u306b\u3057\u59cb\u3081\u308b\uff08\u76f8\u95a2\u3092\u6301\u3064\uff09\u69d8\u5b50\u304c\u89b3\u6e2c\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n\n\n\n

\u3000🔳\u71b1\u306e\u4f1d\u308f\u308a\u65b9\uff08\u71b1\u5bb9\u91cf\uff09\uff1a<\/strong>\u3000 \u666e\u901a\u306e\u78c1\u77f3\u306e\u3088\u3046\u306b\u7279\u5b9a\u306e\u6e29\u5ea6\u3067\u6025\u6fc0\u306b\u5909\u5316\u3057\u3066\u56fa\u307e\u308b\u306e\u3067\u306f\u306a\u304f\u3001\u7d04 -270 \u2103\uff083 K\uff09\u3092\u4e2d\u5fc3\u3068\u3057\u305f\u5e83\u3044\u6e29\u5ea6\u7bc4\u56f2\u3067\u3001\u3060\u3093\u3060\u3093\u3068\u72b6\u614b\u304c\u5909\u5316\u3057\u3066\u3044\u304f\uff08\u30d6\u30ed\u30fc\u30c9\u306a\u30d4\u30fc\u30af\u3092\u793a\u3059\uff09\u3053\u3068\u304c\u78ba\u8a8d\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n\n\n\n

<\/p>\n\n\n\n

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🧲3.<\/strong> \u3053\u306e\u7814\u7a76\u304c\u793a\u3059\u610f\u5473\uff08\u8ad6\u6587\u306e\u7bc4\u56f2\u5185\u3067\uff09<\/strong><\/p>\n\n\n\n

\u5b9f\u9a13\u306e\u7d50\u679c\u304b\u3089\u3001Li\u2082NiGe\u2083O\u2088 \u306f\u300c\u30c8\u30ea\u30ea\u30a6\u30e0\u683c\u5b50\u300d\u3068\u3044\u3046\u7279\u6b8a\u306a\u69cb\u9020\u306e\u4e2d\u3067\u3001\u78c1\u77f3\u306e\u5411\u304d\u304c\u304a\u4e92\u3044\u306b\u5f71\u97ff\u3057\u5408\u3046\u6027\u8cea\uff08\u30d5\u30e9\u30b9\u30c8\u30ec\u30fc\u30b7\u30e7\u30f3\uff09\u3092\u793a\u3059\u6570\u5c11\u306a\u3044\u9178\u5316\u7269\u3067\u3042\u308b\u3053\u3068\u304c\u78ba\u8a8d\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n\n\n\n

\u3053\u306e\u30c7\u30fc\u30bf\u306f\u3001\u7406\u8ad6\u7269\u7406\u5b66\u3067\u8003\u3048\u3089\u308c\u3066\u304d\u305f\u300c\u7b49\u65b9\u7684\u306a\uff08\u7279\u5b9a\u306e\u5411\u304d\u3092\u6301\u305f\u306a\u3044\uff09\u78c1\u77f3\u30e2\u30c7\u30eb\u300d\u3068\u300c\u7570\u65b9\u7684\u306a\uff08\u7279\u5b9a\u306e\u5411\u304d\u3092\u597d\u307f\u3084\u3059\u3044\uff09\u78c1\u77f3\u30e2\u30c7\u30eb\u300d\u306e\u3061\u3087\u3046\u3069\u4e2d\u9593\u306b\u4f4d\u7f6e\u3059\u308b\u3088\u3046\u306a\u6027\u8cea\u3092\u793a\u3057\u3066\u3044\u307e\u3059\u3002\u5b8c\u5168\u306b\u7406\u8ad6\u901a\u308a\u306e\u72b6\u614b\u306b\u306a\u3063\u3066\u3044\u308b\u304b\u3092\u78ba\u304b\u3081\u308b\u305f\u3081\u306b\u306f\u3001\u3055\u3089\u306b\u4f4e\u3044\u6e29\u5ea6\uff08-271 \u2103\u4ee5\u4e0b\uff09\u3067\u306e\u6e2c\u5b9a\u3084\u3001\u3088\u308a\u7d30\u304b\u3044\u30df\u30af\u30ed\u306a\u89b3\u5bdf\u5b9f\u9a13\u304c\u5fc5\u8981\u3067\u3042\u308b\u3068\u793a\u5506\u3055\u308c\u3066\u3044\u307e\u3059\u3002<\/p>\n<\/blockquote>\n\n\n\n

<\/p>\n\n\n\n

\u3000https:\/\/doi.org\/10.7566\/JPSJ.95.074703<\/a><\/strong>\u3000<\/p>\n\n\n\n

🧲Key Points<\/strong><\/p>\n\n\n\n

\n
\n
\n

✅What was studied?:<\/strong>
Researchers synthesized a new oxide material (Li\u2082NiGe\u2083O\u2088) with a unique 3D structure called a
“trillium lattice,” where atomic magnets interfere with each other and cannot easily choose a direction.<\/p>\n\n\n\n

✅What was found?:<\/strong>
As the temperature dropped, the atomic magnets did not abruptly lock into a fixed order. Instead, they gradually influenced each other over a wide temperature range.<\/p>\n\n\n\n

✅Why is it important?:<\/strong>
This material provides a rare real-world oxide platform to compare and test theoretical models of
complex magnetic behavior.<\/p>\n\n\n\n

<\/p>\n<\/div><\/div>\n<\/div><\/div>\n<\/div><\/div>\n\n\n\n

🧲1.Background<\/strong>
When tiny atomic magnets are arranged in specific geometric patterns, they often struggle to choose which direction to point\u2014a phenomenon known as “magnetic frustration.” A specific 3D network called a “trillium lattice” induces strong frustration. While mostly studied in metallic systems, exploring this behavior in insulating oxides makes it easier to compare experimental results directly with theoretical physics models.<\/p>\n\n\n\n

🧲2.Experiments and Results<\/strong>
The research team synthesized polycrystalline samples of Li\u2082NiGe\u2083O\u2088 and measured its crystal structure, magnetization, and heat capacity.<\/p>\n\n\n\n

🔳Structural Analysis:<\/strong> X-ray measurements confirmed that nickel ions form a clean trillium network within an ordered-spinel structure.<\/p>\n\n\n\n

🔳Magnetization:<\/strong> Below approximately 10 K (-263 \u00b0C), the material showed clear signs of short-range magnetic interactions, even though the net exchange field averaged out to nearly zero.<\/p>\n\n\n\n

\u3000🔳Heat Capacity:<\/strong> \u3000Instead of a sharp transition seen in ordinary magnets, the magnetic heat capacity displayed a broad maximum centered near 3 K (-270 \u00b0C), indicating a gradual change in state over a wide temperature range.<\/p>\n\n\n\n

<\/p>\n\n\n\n

\n

🧲3.Implications<\/strong>
Li\u2082NiGe\u2083O\u2088 is a rare example of a single-trillium oxide that displays broad frustrated magnetic correlations.<\/p>\n\n\n\n

These bulk thermodynamic results place the material between two major theoretical frameworks (Heisenberg-like and spin-ice-like models). Further experiments at lower temperatures (below 2 K) and microscopic probes will be needed to fully clarify its underlying low-temperature state.<\/p>\n<\/blockquote>\n\n\n\n

<\/p>\n\n\n\n

\u672c\u8a18\u4e8b\u306f\u3001\u516c\u958b\u6e08\u307f\u8ad6\u6587\u306b\u57fa\u3065\u304d\u5b66\u79d1\u5e83\u5831\u7528\u306b\u7de8\u96c6\u3057\u305f\u7d39\u4ecb\u6587\u3067\u3059\u3002This article is an outreach-style summary prepared for the department website based on the published paper.<\/p>\n\n\n\n

<\/p>\n","protected":false},"excerpt":{"rendered":"

\u306a\u30b8\u30e3\u30f3\u30b0\u30eb\u30b8\u30e0\u69cb\u9020\u3092\u6301\u3064\u65b0\u7269\u8cea Li\u2082NiGe\u2083O\u2088 \u3067\u63a2\u308b\u300c\u78c1\u77f3\u306e\u845b\u85e4\u300d
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