{"id":5551,"date":"2025-02-16T19:15:42","date_gmt":"2025-02-16T10:15:42","guid":{"rendered":"https:\/\/tuat-chemphys.net\/?p=5551"},"modified":"2025-02-16T19:15:42","modified_gmt":"2025-02-16T10:15:42","slug":"phd-%e5%85%ac%e8%81%b4%e4%bc%9a-diffusion-phenomena-in-polyimide-curing-%e3%83%9d%e3%83%aa%e3%82%a4%e3%83%9f%e3%83%89%e8%a3%bd%e8%86%9c%e3%81%ab%e3%81%8a%e3%81%91%e3%82%8b%e6%8b%a1%e6%95%a3%e7%8f%be","status":"publish","type":"post","link":"https:\/\/tuat-chemphys.net\/?p=5551","title":{"rendered":"PhD \u516c\u8074\u4f1a Diffusion Phenomena in Polyimide Curing \u30dd\u30ea\u30a4\u30df\u30c9\u88fd\u819c\u306b\u304a\u3051\u308b\u62e1\u6563\u73fe\u8c61 (2\/19)"},"content":{"rendered":"\n<p>\u56fd\u5206 \u4eae Kokubun, Ryo.<\/p>\n\n\n\n<p>2025\u5e742\u670819\u65e5\uff08\u6c34\u66dc\u65e5\uff0910:30\uff5e12:00 4\u53f7\u99283\u968e\u4ea4\u6d41\u30b9\u30da\u30fc\u30b9<\/p>\n\n\n\n<p><br>\u30dd\u30ea\u30a4\u30df\u30c9\u88fd\u819c\u30d7\u30ed\u30bb\u30b9\u306b\u304a\u3051\u308b\u62e1\u6563\u73fe\u8c61\u306e\u89e3\u6790 A Study on Diffusion Phenomena in the Polyimide Curing Process<br><\/p>\n\n\n\n<p>\u6eb6\u5a92\u30fb\u30dd\u30ea\u30de\u30fc\u9593\u306e\u6c34\u7d20\u7d50\u5408\u5f62\u6210\u3092\u52d8\u6848\u3057\u305f\u81ea\u7531\u4f53\u7a4d\u30e2\u30c7\u30eb\u306e\u69cb\u7bc9\u306b\u3088\u308a\u3001\u30dd\u30ea\u30a4\u30df\u30c9\u5857\u5e03\u4e7e\u71e5\u30d7\u30ed\u30bb\u30b9\u306e\u5f8b\u901f\u904e\u7a0b\u3068\u306a\u308b\u6eb6\u5a92\u5206\u5b50\u62e1\u6563\u306e\u8a18\u8ff0\u306b\u6210\u529f\u3057\u305f\u3002Solvent molecular diffusion, which is the rate-limiting process of the polyimide coating and drying process, was successfully described by constructing a free-volume model considering hydrogen bond formation between solvent and polymer.<\/p>\n\n\n\n<p>RELATED PUBLICATIONS<\/p>\n\n\n\n<p>Study on the Diffusion Coefficients of Molecules in Precursor Varnishes and Solid Polyimides for<br>Understanding the Polyimide Curing Process.<br>Ind. Eng. Chem. Res. 2024, 63 (11), 4934\u20134941. <a href=\"http:\/\/DOI.org\/10.1021\/acs.iecr.3c03748\" data-type=\"link\" data-id=\"DOI.org\/10.1021\/acs.iecr.3c03748\">DOI.org\/10.1021\/acs.iecr.3c03748<\/a>.<br>Kokubu, R.; Hara, N.; Yamamoto, A.; Tomizawa, K.; Matsukawa, S.; Inasawa, S.; Ohashi, H.<br><br>\u30dd\u30ea\u30a4\u30df\u30c9\u53ca\u3073\u305d\u306e\u524d\u99c6\u4f53\u3067\u3042\u308b\u30dd\u30ea\u30a2\u30df\u30c3\u30af\u9178\uff08PAA\uff09\u30ef\u30cb\u30b9\u306e\u62e1\u6563\u4fc2\u6570\u3092\u5b9a\u91cf\u7684\u306b\u89e3\u6790 \u3059\u308b\u3053\u3068\u306f\u3001<br>\u30dd\u30ea\u30a4\u30df\u30c9\u306e\u5de5\u696d\u751f\u7523\u306b\u91cd\u8981\u3067\u3042\u308b\u3002\u672c\u5831\u3067\u306f\u3001\u30b8\u30e1\u30c1\u30eb\u30a2\u30bb\u30c8\u30a2\u30df\u30c9\uff08DMAc\uff09 \u53ca\u3073 PAA \u306e\u62e1\u6563\u4fc2\u6570<br>\u3092\u3001\u30d1\u30eb\u30b9\u78c1\u5834\u52fe\u914d\u6838\u78c1\u6c17\u5171\u9cf4\u6cd5\u3092\u7528\u3044\u3066\u6e2c\u5b9a\u3057\u305f\u3002DMAc \u306e\u62e1\u6563\u4fc2 \u6570\u306f PAA \u6fc3\u5ea6\u306e\u4e0a\u6607\u306b\u4f34<br>\u3063\u3066\u4f4e\u4e0b\u3059\u308b\u304c\u3001\u305d\u306e\u4f9d\u5b58\u6027\u306f\u4e88\u60f3\u4ee5\u4e0a\u306b\u5f37\u304f\u3001DMAc \u306e\u62e1\u6563\u6027 \u306f DMAc \u3068 PAA \u306e\u5f37\u3044\u76f8\u4e92\u4f5c<br>\u7528\u306e\u5f71\u97ff\u3092\u53d7\u3051\u3066\u3044\u308b\u3053\u3068\u304c\u793a\u5506\u3055\u308c\u305f\u3002PAA \u306e\u62e1\u6563\u4fc2\u6570 \u306f\u3001\u30dd\u30ea\u30de\u30fc\u9396\u306e\u7d61\u307f\u5408\u3044\u306b\u3088\u308a PAA<br>\u542b\u6709\u91cf\u306e\u5897\u52a0\u3068\u3068\u3082\u306b\u6e1b\u5c11\u3057\u3001\u7c98\u5ea6\u6e2c\u5b9a\u3067\u78ba\u8a8d\u3055\u308c \u305f\u3002\u30dd\u30ea\u30a4\u30df\u30c9\u30de\u30c8\u30ea\u30c3\u30af\u30b9\u4e2d\u306e DMAc \u306e\u62e1\u6563\u4fc2<br>\u6570\u306f\u3001\u30ad\u30e3\u30d4\u30e9\u30ea\u30fc\u30ab\u30e9\u30e0\u9006\u30ac\u30b9\u30af\u30ed\u30de \u30c8\u30b0\u30e9\u30d5\u30a3\u30fc\u3092\u7528\u3044\u3066\u3001180\uff5e220\u2103\u3067\u6e2c\u5b9a\u3057\u305f\uff0810-12\uff5e10<br>10cm2\/s\uff09\u3002\u3053\u308c\u3089\u306e\u57fa\u790e\u30c7\u30fc\u30bf \u306f\u3001\u30a4\u30df\u30c9\u5316\u30d7\u30ed\u30bb\u30b9\u4e2d\u306e\u5206\u5b50\u62e1\u6563\u3092\u7406\u89e3\u3059\u308b\u4e0a\u3067\u91cd\u8981\u3067\u3042\u308b\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6eb6\u5a92\u30fb\u30dd\u30ea\u30de\u30fc\u9593\u306e\u6c34\u7d20\u7d50\u5408\u5f62\u6210\u3092\u52d8\u6848\u3057\u305f\u81ea\u7531\u4f53\u7a4d\u30e2\u30c7\u30eb\u306e\u69cb\u7bc9\u3002A free-volume model considering hydrogen bond formation between solvent and polymer.<\/p>\n","protected":false},"author":1,"featured_media":4531,"comment_status":"closed","ping_status":"","sticky":false,"template":"","format":"standard","meta":{"advanced_seo_description":"","jetpack_seo_html_title":"","jetpack_seo_noindex":false,"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2}},"categories":[22],"tags":[],"class_list":["post-5551","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-doctoral-thesis-"],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2024\/07\/ohashi-2024.gif?fit=500%2C282&ssl=1","jetpack_sharing_enabled":true,"jetpack-related-posts":[{"id":6764,"url":"https:\/\/tuat-chemphys.net\/?p=6764","url_meta":{"origin":5551,"position":0},"title":"Seminar (2025\/9\/25) Electron Highways in the Dark: Rethinking Anaerobic Digestion \u76f4\u63a5\u7684\u306a\u7a2e\u9593\u96fb\u5b50\u79fb\u52d5\u306b\u3088\u308b\u5acc\u6c17\u6027\u6d88\u5316\u306e\u518d\u8003 (Prof. Changsoo Lee (Ulsan National Institute of Sci. &amp; Tech.)","author":"unet","date":"2025-09","format":false,"excerpt":"DIET\u3068\u306f\u3001\u6c34\u7d20\u3084\u30ae\u9178\u306a\u3069\u306e\u62e1\u6563\u6027\u30e1\u30c7\u30a3\u30a8\u30fc\u30bf\u30fc\u3092\u4ecb\u3055\u305a\u306b\u5fae\u751f\u7269\u9593\u3067\u76f4\u63a5\u96fb\u5b50\u3092\u3084\u308a\u53d6\u308a\u3059\u308b\u4ed5\u7d44\u307f\u3067\u3042\u308a\u3001\u5acc\u6c17\u6027\u30d7\u30ed\u30bb\u30b9\u306e\u6027\u80fd\u5411\u4e0a\u3068\u5fdc\u7528\u62e1\u5927\u306b\u65b0\u305f\u306a\u53ef\u80fd\u6027\u3092\u3082\u305f\u3089\u3057\u307e\u3059\u3002DIET is a mechanism by which microorganisms exchange electrons directly, without relying on diffusible mediators like hydrogen or formate.","rel":"","context":"In &quot;Guest Seminar&quot;","block_context":{"text":"Guest Seminar","link":"https:\/\/tuat-chemphys.net\/?cat=8"},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/09\/%E3%82%B9%E3%82%AF%E3%83%AA%E3%83%BC%E3%83%B3%E3%82%B7%E3%83%A7%E3%83%83%E3%83%88-2025-09-22-19.24.46.png?fit=1200%2C873&ssl=1&resize=350%2C200","width":350,"height":200,"srcset":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/09\/%E3%82%B9%E3%82%AF%E3%83%AA%E3%83%BC%E3%83%B3%E3%82%B7%E3%83%A7%E3%83%83%E3%83%88-2025-09-22-19.24.46.png?fit=1200%2C873&ssl=1&resize=350%2C200 1x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/09\/%E3%82%B9%E3%82%AF%E3%83%AA%E3%83%BC%E3%83%B3%E3%82%B7%E3%83%A7%E3%83%83%E3%83%88-2025-09-22-19.24.46.png?fit=1200%2C873&ssl=1&resize=525%2C300 1.5x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/09\/%E3%82%B9%E3%82%AF%E3%83%AA%E3%83%BC%E3%83%B3%E3%82%B7%E3%83%A7%E3%83%83%E3%83%88-2025-09-22-19.24.46.png?fit=1200%2C873&ssl=1&resize=700%2C400 2x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/09\/%E3%82%B9%E3%82%AF%E3%83%AA%E3%83%BC%E3%83%B3%E3%82%B7%E3%83%A7%E3%83%83%E3%83%88-2025-09-22-19.24.46.png?fit=1200%2C873&ssl=1&resize=1050%2C600 3x"},"classes":[]},{"id":7493,"url":"https:\/\/tuat-chemphys.net\/?p=7493","url_meta":{"origin":5551,"position":1},"title":"\u30b3\u30ed\u30a4\u30c9\u7c92\u5b50\u3092\u542b\u3080\u9ad8\u5206\u5b50\u6eb6\u6db2\u306e\u300c\u4e7e\u71e5\u901f\u5ea6\u300d\u306f\u306a\u305c\u5909\u308f\u308b\uff1fWhy Do Polymer Solutions with Colloidal Particles Dry Differently?","author":"unet","date":"2026-02","format":false,"excerpt":"\u30b3\u30ed\u30a4\u30c9\u7c92\u5b50\u5165\u308a\u9ad8\u5206\u5b50\u6eb6\u6db2\u306f\u3001\u306a\u305c\u4e7e\u71e5\u304c\u65e9\u304f\u9045\u304f\u306a\u308b\uff1f \u305d\u306e\u201c\u81e8\u754c\u91cf\u201d\u3068\u666e\u904d\u7684\u3075\u308b\u307e\u3044\u3092\u89e3\u660e\uff01Why do polymer solutions with colloids dry differently? This study reveals the \u201ccritical threshold\u201d and universal behavior.","rel":"","context":"In &quot;Research Topics&quot;","block_context":{"text":"Research Topics","link":"https:\/\/tuat-chemphys.net\/?cat=9"},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2026\/02\/image-8.png?fit=500%2C268&ssl=1&resize=350%2C200","width":350,"height":200},"classes":[]},{"id":7013,"url":"https:\/\/tuat-chemphys.net\/?p=7013","url_meta":{"origin":5551,"position":2},"title":"\u5b66\u751f\u304c\u3001\u56fd\u5185\u5916\u306e\u5b66\u4f1a\u3084\u30b7\u30f3\u30dd\u30b8\u30a6\u30e0\u3067\u591a\u6570\u306e\u8cde\u3092\u53d7\u8cde\u3057\u307e\u3057\u305f Students have received numerous awards at national and international conferences in 2025.","author":"unet","date":"2025-12","format":false,"excerpt":"Students have received numerous awards at national and international conferences in 2025. Here are the highlights:","rel":"","context":"In &quot;Awards&quot;","block_context":{"text":"Awards","link":"https:\/\/tuat-chemphys.net\/?cat=3"},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/12\/image-2.png?fit=732%2C313&ssl=1&resize=350%2C200","width":350,"height":200,"srcset":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/12\/image-2.png?fit=732%2C313&ssl=1&resize=350%2C200 1x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/12\/image-2.png?fit=732%2C313&ssl=1&resize=525%2C300 1.5x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/12\/image-2.png?fit=732%2C313&ssl=1&resize=700%2C400 2x"},"classes":[]},{"id":6613,"url":"https:\/\/tuat-chemphys.net\/?p=6613","url_meta":{"origin":5551,"position":3},"title":"Our presentations: \u30a8\u30cd\u30eb\u30ae\u30fc\u5b66\u4f1a\u3001\u5fdc\u7528\u7269\u7406\u5b66\u4f1a\u3001\u96fb\u5b50\u60c5\u5831\u901a\u4fe1\u5b66\u4f1a\u3001\u96fb\u6c17\u5b66\u3001\u5316\u5b66\u5de5\u5b66\u4f1a\u3001\u7269\u7406\u5b66\u4f1a\u7b49","author":"unet","date":"2025-08","format":false,"excerpt":"At Japan Institute of Energy, Society of Applied Physics, IEICE Society Conference, Soc. Chemical Engineers, Physical Society of Japan, etc.","rel":"","context":"In &quot;Research Topics&quot;","block_context":{"text":"Research Topics","link":"https:\/\/tuat-chemphys.net\/?cat=9"},"img":{"alt_text":"Earth Day Presentation","src":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/08\/3468651131_cd3427b484_b.jpg?fit=1023%2C432&ssl=1&resize=350%2C200","width":350,"height":200,"srcset":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/08\/3468651131_cd3427b484_b.jpg?fit=1023%2C432&ssl=1&resize=350%2C200 1x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/08\/3468651131_cd3427b484_b.jpg?fit=1023%2C432&ssl=1&resize=525%2C300 1.5x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/08\/3468651131_cd3427b484_b.jpg?fit=1023%2C432&ssl=1&resize=700%2C400 2x"},"classes":[]},{"id":6867,"url":"https:\/\/tuat-chemphys.net\/?p=6867","url_meta":{"origin":5551,"position":4},"title":"\u79cb\u306e\u30aa\u30fc\u30d7\u30f3\u30ad\u30e3\u30f3\u30d1\u30b9\u3068\u30da\u30a2\u30ec\u30f3\u30c4\u30c7\u30fc 2025\/11\/9 Open Campus\/Labs","author":"unet","date":"2025-10","format":false,"excerpt":"\u7814\u7a76\u5ba4\u3092\u4e00\u6319\u3054\u7d39\u4ecb","rel":"","context":"In &quot;Event\/News&quot;","block_context":{"text":"Event\/News","link":"https:\/\/tuat-chemphys.net\/?cat=4"},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/10\/image.png?fit=711%2C1005&ssl=1&resize=350%2C200","width":350,"height":200,"srcset":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/10\/image.png?fit=711%2C1005&ssl=1&resize=350%2C200 1x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/10\/image.png?fit=711%2C1005&ssl=1&resize=525%2C300 1.5x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/10\/image.png?fit=711%2C1005&ssl=1&resize=700%2C400 2x"},"classes":[]},{"id":6390,"url":"https:\/\/tuat-chemphys.net\/?p=6390","url_meta":{"origin":5551,"position":5},"title":"\u5316\u5b66\u5de5\u5b66\u4f1a \u7b2c90\u5e74\u4f1a\u306b\u767a\u8868\u3057\u307e\u3057\u305f\u3002Our presentations at SCEJ 90th Annual Meeting, March 2025","author":"unet","date":"2025-03","format":false,"excerpt":"\u5316\u5b66\u5de5\u5b66\u4f1a \u7b2c90\u5e74\u4f1a\u306b\u767a\u8868\u3057\u307e\u3057\u305f\u3002Our presentations at SCEJ 90th Annual Meeting, March 2025","rel":"","context":"In &quot;Research Topics&quot;","block_context":{"text":"Research Topics","link":"https:\/\/tuat-chemphys.net\/?cat=9"},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/07\/image-6-1024x85.png?resize=350%2C200&ssl=1","width":350,"height":200,"srcset":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/07\/image-6-1024x85.png?resize=350%2C200&ssl=1 1x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/07\/image-6-1024x85.png?resize=525%2C300&ssl=1 1.5x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/07\/image-6-1024x85.png?resize=700%2C400&ssl=1 2x"},"classes":[]}],"jetpack_shortlink":"https:\/\/wp.me\/pa3J4g-1rx","jetpack_likes_enabled":true,"_links":{"self":[{"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/posts\/5551","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=5551"}],"version-history":[{"count":1,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/posts\/5551\/revisions"}],"predecessor-version":[{"id":5552,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/posts\/5551\/revisions\/5552"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=\/wp\/v2\/media\/4531"}],"wp:attachment":[{"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=5551"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=5551"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/tuat-chemphys.net\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=5551"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}