{"id":3455,"date":"2023-09-22T10:23:44","date_gmt":"2023-09-22T01:23:44","guid":{"rendered":"http:\/\/tuat-chemphys.net\/?p=3455"},"modified":"2023-09-22T10:23:44","modified_gmt":"2023-09-22T01:23:44","slug":"%e6%9c%89%e6%a9%9f%e5%a4%aa%e9%99%bd%e9%9b%bb%e6%b1%a0%e3%81%ae%e7%a7%98%e5%af%86%e3%82%92%e8%a7%a3%e3%81%8d%e6%98%8e%e3%81%8b%e3%81%99-unveiling-the-secrets-of-organic-photovoltaic-cells-acs-appl-e","status":"publish","type":"post","link":"https:\/\/tuat-chemphys.net\/?p=3455","title":{"rendered":"\u6709\u6a5f\u592a\u967d\u96fb\u6c60\u306e\u79d8\u5bc6\u3092\u89e3\u304d\u660e\u304b\u3059 Unveiling the Secrets of Organic Photovoltaic Cells (ACS Appl. Energy Mater.)"},"content":{"rendered":"\n

\u6709\u6a5f\u7cfb\u592a\u967d\u96fb\u6c60\uff08OPV\uff09\u306f\u3001\u30d7\u30e9\u30b9\u30c1\u30c3\u30af\u306a\u3069\u306e\u6709\u6a5f\u6750\u6599\u3067\u4f5c\u3089\u308c\u305f\u65b0\u3057\u3044\u30bf\u30a4\u30d7\u306e\u592a\u967d\u96fb\u6c60\u3067\u3059\u3002OPV\u306f\u3001\u307e\u3060\u958b\u767a\u9014\u4e0a\u3067\u3059\u304c\u3001\u5f93\u6765\u306e\u30b7\u30ea\u30b3\u30f3\u592a\u967d\u96fb\u6c60\u3088\u308a\u3082\u5b89\u4fa1\u3067\u67d4\u8edf\u306a\u7279\u6027\u3092\u6301\u3063\u3066\u3044\u308b\u305f\u3081\u3001\u5c06\u6765\u6709\u671b\u306a\u6280\u8853\u3068\u3057\u3066\u6ce8\u76ee\u3055\u308c\u3066\u3044\u307e\u3059\u3002Organic photovoltaic cells (OPVs) are a new type of solar cell that is made from organic materials, such as plastics. OPVs are still under development, but they have the potential to be cheaper and more flexible than traditional silicon solar cells.<\/p>\n\n\n\n

OPV\u306e\u958b\u767a\u306b\u304a\u3044\u3066\u3001\u6700\u3082\u91cd\u8981\u306a\u8ab2\u984c\u306e\u4e00\u3064\u306f\u3001\u30d0\u30eb\u30af\u30d8\u30c6\u30ed\u63a5\u5408\u5c64\u306e\u69cb\u9020\uff08BHJ\u69cb\u9020\uff09\u3092\u5236\u5fa1\u3059\u308b\u3053\u3068\u3067\u3059\u3002BHJ\u306f\u3001OPV\u306b\u304a\u3044\u3066\u5149\u304c\u5438\u53ce\u3055\u308c\u3001\u96fb\u6c17\u30a8\u30cd\u30eb\u30ae\u30fc\u306b\u5909\u63db\u3055\u308c\u308b\u5c64\u3067\u3059\u3002BHJ\u306f\u3001\u30c9\u30ca\u30fc\u6750\u6599\u3068\u30a2\u30af\u30bb\u30d7\u30bf\u30fc\u6750\u6599\u306e2\u7a2e\u985e\u306e\u6709\u6a5f\u6750\u6599\u304b\u3089\u69cb\u6210\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u30c9\u30ca\u30fc\u6750\u6599\u306f\u5149\u3092\u5438\u53ce\u3057\u3066\u96fb\u5b50\u3092\u4f5c\u308a\u51fa\u3057\u3001\u30a2\u30af\u30bb\u30d7\u30bf\u30fc\u6750\u6599\u306f\u96fb\u5b50\u3092\u53d7\u3051\u53d6\u3063\u3066OPV\u306e\u96fb\u6975\u306b\u904b\u642c\u3057\u307e\u3059\u3002Organic photovoltaic cells (OPVs) are a new type of solar cell that is made from organic materials, such as plastics. OPVs are still under development, but they have the potential to be cheaper and more flexible than traditional silicon solar cells.<\/p>\n\n\n\n

OPV\u306e\u52b9\u7387\u306f\u3001BHJ\u69cb\u9020\u306b\u4f9d\u5b58\u3057\u307e\u3059\u3002BHJ\u306f\u3001\u3067\u304d\u308b\u3060\u3051\u591a\u304f\u306e\u5149\u3092\u5438\u53ce\u3067\u304d\u308b\u3088\u3046\u306b\u3001\u8868\u9762\u7a4d\u304c\u5927\u304d\u304f\u306a\u3051\u308c\u3070\u306a\u308a\u307e\u305b\u3093\u3002\u307e\u305f\u3001\u96fb\u5b50\u3092\u30c9\u30ca\u30fc\u304b\u3089\u30a2\u30af\u30bb\u30d7\u30bf\u30fc\u306b\u52b9\u7387\u7684\u306b\u79fb\u52d5\u3055\u305b\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u3088\u3046\u306b\u3001\u30c9\u30ca\u30fc\u3068\u30a2\u30af\u30bb\u30d7\u30bf\u30fc\u6750\u6599\u306e\u8ddd\u96e2\u304c\u77ed\u304f\u306a\u3051\u308c\u3070\u306a\u308a\u307e\u305b\u3093\u3002One of the key challenges in developing OPVs is controlling the bulk heterojunction (BHJ) structure. The BHJ is the layer of the OPV where the light is absorbed and converted into electricity. The BHJ is made up of two different types of organic materials: a donor material and an acceptor material. The donor material absorbs the light and generates electrons. The acceptor material accepts the electrons and transports them to the electrodes of the OPV.<\/p>\n\n\n

\n
\"\"<\/a>
https:\/\/doi.org\/10.1021\/acsaem.3c01262<\/a><\/figcaption><\/figure>\n<\/div>\n\n\n

\u4eca\u56de\u306e\u7814\u7a76\u3067\u306f\u3001\u7b95\u7530\u7814\u7a76\u5ba4\u304c\u958b\u767a\u3057\u305f\u30d5\u30a7\u30fc\u30ba\u30d7\u30ec\u30fc\u30c8\u8d70\u67fb\u900f\u904e\u578b\u96fb\u5b50\u9855\u5fae\u93e1\uff08P-STEM\uff09\u3068\u547c\u3070\u308c\u308b\u6280\u8853\u3092\u4f7f\u7528\u3057\u3066\u3001OPV\u306eBHJ\u69cb\u9020\u3092\u53ef\u8996\u5316\u3057\u307e\u3057\u305f\u3002P-STEM\u306f\u3001\u6750\u6599\u3092\u539f\u5b50\u30ec\u30d9\u30eb\u3067\u753b\u50cf\u5316\u3059\u308b\u305f\u3081\u306b\u4f7f\u7528\u3067\u304d\u308b\u5f37\u529b\u306a\u6280\u8853\u3067\u3059\u3002In this study, the researchers (Minoda Lab and Kaji Lab) used a powerful technique called phase plate scanning transmission electron microscopy (P-STEM) to image the BHJ structure of an OPV at the atomic level. They found that the BHJ structure is very complex, with a hybrid layer of donor and acceptor materials at the interface.<\/p>\n\n\n\n

\u7b95\u7530\u7814\u7a76\u5ba4\u3068\u5609\u6cbb\u7814\u7a76\u5ba4\u306e\u7686\u3055\u3093\u306f\u3001\u91d1\u5c5e\u30d5\u30ea\u30fc\u30d5\u30bf\u30ed\u30b7\u30a2\u30cb\u30f3\uff08H2Pc\uff09\u3092\u30c9\u30ca\u30fc\u6750\u6599\u3001\u30d5\u30e9\u30fc\u30ec\u30f3\uff08C60\uff09\u3092\u30a2\u30af\u30bb\u30d7\u30bf\u30fc\u6750\u6599\u3068\u3057\u3066\u4f5c\u88fd\u3057\u305f\u30b5\u30d6\u30df\u30af\u30ed\u30f3\uff08\u6570\u767e\u30ca\u30ce\u30e1\u30fc\u30bf\u30fc\uff09\u539a\u306eOPV\u3092P-STEM\u3067\u753b\u50cf\u5316\u3057\u307e\u3057\u305f\u3002\u305d\u306e\u7d50\u679c\u3001OPV\u306eBHJ\u69cb\u9020\u306f\u975e\u5e38\u306b\u8907\u96d1\u3067\u3042\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f\u3002\u30c9\u30ca\u30fc\u6750\u6599\u3068\u30a2\u30af\u30bb\u30d7\u30bf\u30fc\u6750\u6599\u306e\u754c\u9762\u306b\u306f\u3001H2Pc\u3068C60\u306e\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u5c64\u304c\u5b58\u5728\u3057\u3066\u3044\u307e\u3057\u305f\u3002\u3053\u306e\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u5c64\u306f\u3001\u819c\u6210\u9577\u306e\u521d\u671f\u6bb5\u968e\u306b\u300c\u81e8\u754c\u819c\u539a\u300d\u306b\u9054\u3059\u308b\u307e\u3067\u5f62\u6210\u3055\u308c\u3001\u305d\u306e\u5f8c\u3001\u76f8\u5206\u96e2\u3057\u305f\u898f\u5247\u7684\u306aBHJ\u304c\u6210\u9577\u3057\u307e\u3057\u305f\u3002<\/p>\n\n\n\n

\u3053\u306e\u89b3\u5bdf\u7d50\u679c\u306f\u3001P-STEM\u304c\u6709\u6a5f\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u6750\u6599\u306e\u5206\u6790\u306b\u5927\u304d\u306a\u53ef\u80fd\u6027\u3092\u79d8\u3081\u3066\u3044\u308b\u3053\u3068\u3092\u793a\u3057\u3066\u3044\u307e\u3059\u3002P-STEM\u306f\u3001OPV\u306eBHJ\u69cb\u9020\u3092\u8a73\u7d30\u306b\u7814\u7a76\u3059\u308b\u305f\u3081\u306b\u4f7f\u7528\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u3001\u3053\u308c\u306f\u3088\u308a\u52b9\u7387\u7684\u306aOPV\u306e\u958b\u767a\u306b\u5f79\u7acb\u3064\u3067\u3057\u3087\u3046\u3002This observation demonstrates the potential of P-STEM for analyzing organic hybrid materials, such as the BHJ in OPVs. By studying the BHJ structure in detail, researchers can develop more efficient OPVs.<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

Visualization of Tens of Nanometers Spaced Donor: Acceptor Bulk Heterojunctions across Submicrometer-Square Cross Sections of Organic Photovoltaic Cells<\/strong> (Natsuki Kumagai, Toshiki Shimizu, Hiroki Minoda*, Mikimasa Katayama, Satoru Nakao, and Toshihiko Kaji) ACS Appl. Energy Mater. 2023 https:\/\/doi.org\/10.1021\/acsaem.3c01262<\/a><\/p>\n\n\n\n

Supporting Info\/\u88dc\u52a9\u8aac\u660e\u8cc7\u6599\uff08free-download\uff09<\/p>\n\n\n\n

https:\/\/pubs.acs.org\/doi\/10.1021\/acsaem.3c01262?goto=supporting-info<\/a><\/p>\n\n\n\n

<\/p>\n\n\n\n

Text: WL<\/p>\n","protected":false},"excerpt":{"rendered":"

\u30d5\u30a7\u30fc\u30ba\u30d7\u30ec\u30fc\u30c8\u8d70\u67fb\u900f\u904e\u578b\u96fb\u5b50\u9855\u5fae\u93e1P-STEM\u304c\u6709\u6a5f\u30cf\u30a4\u30d6\u30ea\u30c3\u30c9\u6750\u6599\u306e\u5206\u6790\u306b\u5927\u304d\u306a\u53ef\u80fd\u6027\u3092\u79d8\u3081\u3066\u3044\u308b\u3002The potential of P-STEM (phase plate scanning transmission electron microscopy) for analyzing organic hybrid materials (bulk heterojunction in organic photovoltaic cells).<\/p>\n","protected":false},"author":3,"featured_media":3459,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"advanced_seo_description":"","jetpack_seo_html_title":"","jetpack_seo_noindex":false,"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2}},"categories":[9],"tags":[12,14,16],"class_list":["post-3455","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-research","tag-energy-conversion-optimization","tag-advanced-materials-creation","tag-measurement-devices"],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2023\/09\/pexels-photo-9875413.jpeg?fit=1733%2C1300&ssl=1","jetpack_sharing_enabled":true,"jetpack-related-posts":[{"id":6478,"url":"https:\/\/tuat-chemphys.net\/?p=6478","url_meta":{"origin":3455,"position":0},"title":"Eco-friendly AgBiS\u2082 nanocrystals with photodetector performance. \u74b0\u5883\u306b\u3084\u3055\u3057\u3044AgBiS\u2082\u30ca\u30ce\u7d50\u6676\u3092\u958b\u767a\u3001\u5149\u96fb\u5b50\u30c7\u30d0\u30a4\u30b9\u306e\u672a\u6765\u306b\u671f\u5f85","author":"unet","date":"2025-08","format":false,"excerpt":"\u4eca\u5f8c\u306f\u3001\u30ca\u30ce\u7d50\u6676\u306e\u30b5\u30a4\u30ba\u5236\u5fa1\u6280\u8853\u306e\u958b\u767a\u3092\u9032\u3081\u3001\u74b0\u5883\u306b\u914d\u616e\u3057\u305f\u9ad8\u6027\u80fd\u5149\u96fb\u5b50\u30c7\u30d0\u30a4\u30b9\u306e\u5b9f\u73fe\u3092\u76ee\u6307\u3057\u307e\u3059\u3002Future work will focus on developing size control techniques for nanocrystals to realize environmentally friendly, high-performance optoelectronic devices.","rel":"","context":"In "Research Topics"","block_context":{"text":"Research Topics","link":"https:\/\/tuat-chemphys.net\/?cat=9"},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/08\/image.png?fit=600%2C472&ssl=1&resize=350%2C200","width":350,"height":200,"srcset":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/08\/image.png?fit=600%2C472&ssl=1&resize=350%2C200 1x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/08\/image.png?fit=600%2C472&ssl=1&resize=525%2C300 1.5x"},"classes":[]},{"id":6684,"url":"https:\/\/tuat-chemphys.net\/?p=6684","url_meta":{"origin":3455,"position":1},"title":"\u3088\u308a\u591a\u304f\u306e\u592a\u967d\u5149\u3092\u6355\u6349\u3059\u308b\u592a\u967d\u5149\u96c6\u5149\u5668 Solar Concentrators: Capturing More Sunlight","author":"unet","date":"2025-09","format":false,"excerpt":"\u958b\u767a\u3055\u308c\u305f\u300cMultiPro-CPC\u300d\u96c6\u5149\u5668\u306e\u4e3b\u8981\u306a\u9769\u65b0\u306f\u3001\u65b9\u5411\u306b\u3088\u3063\u3066\u7570\u306a\u308b\u53d7\u5149\u89d2\u3092\u6301\u3066\u308b\u3053\u3068\u3067\u3059\u3002The \"MultiPro-CPCs\" (Multi-Profile Compound Parabolic Concentrators) can have different acceptance angles in different directions.","rel":"","context":"In "Research Topics"","block_context":{"text":"Research Topics","link":"https:\/\/tuat-chemphys.net\/?cat=9"},"img":{"alt_text":"","src":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/09\/image.png?fit=1135%2C387&ssl=1&resize=350%2C200","width":350,"height":200,"srcset":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/09\/image.png?fit=1135%2C387&ssl=1&resize=350%2C200 1x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/09\/image.png?fit=1135%2C387&ssl=1&resize=525%2C300 1.5x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/09\/image.png?fit=1135%2C387&ssl=1&resize=700%2C400 2x, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2025\/09\/image.png?fit=1135%2C387&ssl=1&resize=1050%2C600 3x"},"classes":[]},{"id":7181,"url":"https:\/\/tuat-chemphys.net\/?p=7181","url_meta":{"origin":3455,"position":2},"title":"Assoc. 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