{"id":1165,"date":"2021-01-24T21:04:05","date_gmt":"2021-01-24T12:04:05","guid":{"rendered":"http:\/\/tuat-chemphys.net\/?p=1165"},"modified":"2021-01-24T21:04:05","modified_gmt":"2021-01-24T12:04:05","slug":"%e7%87%83%e6%96%99%e9%9b%bb%e6%b1%a0%e3%81%ae%e6%a9%9f%e6%a7%8b%e3%81%ae%e8%a7%a3%e6%98%8e%ef%bc%9a%e3%83%97%e3%83%ad%e3%83%88%e3%83%b3%e4%be%9b%e4%b8%8e%e4%bd%93%e3%81%af%e8%a4%87%e6%95%b0%e3%81%ae","status":"publish","type":"post","link":"https:\/\/tuat-chemphys.net\/?p=1165","title":{"rendered":"\uff08\u71c3\u6599\u96fb\u6c60\u5411\u3051\uff09\u30d7\u30ed\u30c8\u30f3\u4f9b\u4e0e\u4f53\u306f\u8907\u6570\u306e\u6c34\u7d20\u7d50\u5408\u3092\u4ecb\u3057\u3066\u9593\u63a5\u7684\u306b\u76f8\u4e92\u4f5c\u7528\u3059\u308b Proton donors indirectly interact with each other through several hydrogen-bonds (for Fuel Cells) \u6587\u8cac:\u5927\u5b66\u9662\u751fN.S."},"content":{"rendered":"\n<p>\u56fa\u4f53\u9178\u5316\u7269\u71c3\u6599\u96fb\u6c60\uff08SOFC\uff09\u306f\u71c3\u6599\u96fb\u6c60\u306e\u4e2d\u3067\u6700\u3082\u767a\u96fb\u52b9\u7387\u304c\u9ad8\u304f\u3001\u5730\u7403\u6e29\u6696\u5316\u6291\u5236\u6280\u8853\u3068\u3057\u3066\u6ce8\u76ee\u3092\u96c6\u3081\u3066\u3044\u308b\u3002SOFC\u306b\u306f\u69d8\u3005\u306a\u7a2e\u985e\u304c\u3042\u308b\u304c\u3001\u51fa\u529b\u5bc6\u5ea6\u3084\u71c3\u6599\u5229\u7528\u7387\u304c\u9ad8\u3044\u3082\u306e\u3068\u3057\u3066\u30d7\u30ed\u30c8\u30f3\u4f1d\u5c0e\u578bSOFC\u304c\u77e5\u3089\u308c\u3066\u3044\u308b\u30022\u3064\u306e\u96fb\u6975\u306f\u96fb\u89e3\u8cea\u3067\u9694\u3066\u3089\u308c\u3066\u304a\u308a\u3001\u96fb\u89e3\u8cea\u3067\u306e\u6c34\u7d20\u30a4\u30aa\u30f3\u306e\u79fb\u52d5\u306f\u96fb\u6c60\u6027\u80fd\u306b\u5927\u304d\u304f\u5f71\u97ff\u3059\u308b\u3002<\/p>\n\n\n\n<p>\u30d2\u30c9\u30ed\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u3084\u30b9\u30eb\u30db\u30f3\u9178\u3001\u30ea\u30f3\u9178\u57fa\u306a\u3069\u306e\u6c34\u7d20\u30a4\u30aa\u30f3\u4f9b\u4e0e\u4f53\u304c\u9ad8\u6fc3\u5ea6\u306b\u5b58\u5728\u3059\u308b\u74b0\u5883\u4e0b\u3067\u306f\u3001\u9178-\u9178\u76f8\u4e92\u4f5c\u7528\u3092\u4ecb\u3057\u3066\u6c34\u7d20\u30a4\u30aa\u30f3\u304c\u4f1d\u5c0e\u3059\u308b\u300c\u30d1\u30c3\u30af\u30c9\u9178\u6a5f\u69cb\u300d\u304c\u63d0\u6848\u3055\u308c\u3066\u3044\u308b\u3002\u3053\u308c\u306f\u6c34\u7d20\u30a4\u30aa\u30f3\u4f9b\u4e0e\u4f53\u540c\u58eb\u306e\u8ddd\u96e2\u304c\u8fd1\u304f\u3001\u76f4\u63a5\u6c34\u7d20\u7d50\u5408\u304c\u5f62\u6210\u3055\u308c\u305f\u5834\u5408\u306b\u306e\u307f\u8d77\u3053\u308b\u3068\u3055\u308c\u3066\u3044\u305f\u304c\u3001\u5927\u6a4b\u51c6\u6559\u6388\u3089\u306e\u7814\u7a76\u306b\u3088\u308a\u8ddd\u96e2\u304c\u96e2\u308c\u3066\u3044\u3066\u3082\u8907\u6570\u306e\u6c34\u7d20\u7d50\u5408\u3092\u4ecb\u3057\u3066\u9593\u63a5\u7684\u306b\u76f8\u4e92\u4f5c\u7528\u3067\u304d\u308b\u3053\u3068\u304c\u660e\u3089\u304b\u306b\u306a\u3063\u305f\u3002<\/p>\n\n\n\n<p>\u672c\u7814\u7a76\u6210\u679c\u306f\u3001\u4e0a\u8a18\u306e\u71c3\u6599\u96fb\u6c60\u6750\u6599\u306e\u958b\u767a\u306b\u6d3b\u304b\u3055\u308c\u308b\u4ed6\u3001<strong>\u30bf\u30f3\u30d1\u30af\u8cea\u5185\u306e\u6c34\u7d20\u30a4\u30aa\u30f3\u7d4c\u8def\u306e\u9178\u5869\u57fa\u914d\u7f6e\u3092\u89e3\u660e\u3059\u308b<\/strong>\u53ef\u80fd\u6027\u304c\u3042\u308b\u306a\u3069\u3001\u30a8\u30f3\u30b8\u30cb\u30a2\u30ea\u30f3\u30b0\u304b\u3089\u30b5\u30a4\u30a8\u30f3\u30b9\u307e\u3067\u69d8\u3005\u306a\u5206\u91ce\u306e\u7814\u7a76\u306b\u8ca2\u732e\u3059\u308b\u3053\u3068\u304c\u671f\u5f85\u3055\u308c\u308b\u3002<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter size-large\"><img data-recalc-dims=\"1\" loading=\"lazy\" decoding=\"async\" width=\"810\" height=\"261\" data-attachment-id=\"1166\" data-permalink=\"https:\/\/tuat-chemphys.net\/?attachment_id=1166\" data-orig-file=\"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-gr4_lrg.jpg?fit=2067%2C667&amp;ssl=1\" data-orig-size=\"2067,667\" data-comments-opened=\"1\" data-image-meta=\"{&quot;aperture&quot;:&quot;0&quot;,&quot;credit&quot;:&quot;&quot;,&quot;camera&quot;:&quot;&quot;,&quot;caption&quot;:&quot;&quot;,&quot;created_timestamp&quot;:&quot;0&quot;,&quot;copyright&quot;:&quot;&quot;,&quot;focal_length&quot;:&quot;0&quot;,&quot;iso&quot;:&quot;0&quot;,&quot;shutter_speed&quot;:&quot;0&quot;,&quot;title&quot;:&quot;&quot;,&quot;orientation&quot;:&quot;0&quot;}\" data-image-title=\"1-s2.0-S0009261419305998-gr4_lrg\" data-image-description=\"\" data-image-caption=\"\" data-large-file=\"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-gr4_lrg.jpg?fit=810%2C261&amp;ssl=1\" src=\"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-gr4_lrg.jpg?resize=810%2C261&#038;ssl=1\" alt=\"\" class=\"wp-image-1166\" srcset=\"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-gr4_lrg.jpg?resize=1024%2C330&amp;ssl=1 1024w, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-gr4_lrg.jpg?resize=300%2C97&amp;ssl=1 300w, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-gr4_lrg.jpg?resize=768%2C248&amp;ssl=1 768w, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-gr4_lrg.jpg?resize=1536%2C496&amp;ssl=1 1536w, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-gr4_lrg.jpg?resize=2048%2C661&amp;ssl=1 2048w, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-gr4_lrg.jpg?w=1620&amp;ssl=1 1620w\" sizes=\"auto, (max-width: 810px) 100vw, 810px\" \/><figcaption>Illustrations of the typical proton conduction triggered by indirect acid-acid interactions. It is assumed that a proton conducts from left to right through the ordered water molecules in the center.&nbsp;\u9178\u3068\u9178\u306e\u9593\u63a5\u7684\u306a\u76f8\u4e92\u4f5c\u7528\u306b\u3088\u3063\u3066\u5f15\u304d\u8d77\u3053\u3055\u308c\u308b\u5178\u578b\u7684\u306a\u30d7\u30ed\u30c8\u30f3\u4f1d\u5c0e\u306e\u56f3\uff08\u30d7\u30ed\u30c8\u30f3\u304c\u4e2d\u592e\u306e\u79e9\u5e8f\u5316\u3055\u308c\u305f\u6c34\u5206\u5b50\u3092\u5de6\u304b\u3089\u53f3\u306b\u4f1d\u5c0e\u3059\u308b\u3068\u4eee\u5b9a\uff09<\/figcaption><\/figure><\/div>\n\n\n\n<p>Solid oxide fuel cells (SOFCs) have the highest power generation efficiency among fuel cells, and are attracting attention as a technology to reduce global warming. There are various types of SOFCs, but proton-conducting SOFCs are known for their high power density and fuel utilization. The two electrodes are separated by an electrolyte, and the movement of hydrogen ions in the electrolyte has a significant impact on the battery performance. The two electrodes are separated by an electrolyte, and the movement of hydrogen ions in the electrolyte has a significant effect on the battery performance.<\/p>\n\n\n\n<div class=\"wp-block-image\"><figure class=\"aligncenter size-large\"><img data-recalc-dims=\"1\" loading=\"lazy\" decoding=\"async\" width=\"810\" height=\"384\" data-attachment-id=\"1168\" data-permalink=\"https:\/\/tuat-chemphys.net\/?attachment_id=1168\" data-orig-file=\"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-ga1_lrg.jpg?fit=1118%2C531&amp;ssl=1\" data-orig-size=\"1118,531\" data-comments-opened=\"1\" data-image-meta=\"{&quot;aperture&quot;:&quot;0&quot;,&quot;credit&quot;:&quot;&quot;,&quot;camera&quot;:&quot;&quot;,&quot;caption&quot;:&quot;&quot;,&quot;created_timestamp&quot;:&quot;0&quot;,&quot;copyright&quot;:&quot;&quot;,&quot;focal_length&quot;:&quot;0&quot;,&quot;iso&quot;:&quot;0&quot;,&quot;shutter_speed&quot;:&quot;0&quot;,&quot;title&quot;:&quot;&quot;,&quot;orientation&quot;:&quot;0&quot;}\" data-image-title=\"1-s2.0-S0009261419305998-ga1_lrg\" data-image-description=\"\" data-image-caption=\"\" data-large-file=\"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-ga1_lrg.jpg?fit=810%2C384&amp;ssl=1\" src=\"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-ga1_lrg.jpg?resize=810%2C384&#038;ssl=1\" alt=\"\" class=\"wp-image-1168\" srcset=\"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-ga1_lrg.jpg?resize=1024%2C486&amp;ssl=1 1024w, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-ga1_lrg.jpg?resize=300%2C142&amp;ssl=1 300w, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-ga1_lrg.jpg?resize=768%2C365&amp;ssl=1 768w, https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-ga1_lrg.jpg?w=1118&amp;ssl=1 1118w\" sizes=\"auto, (max-width: 810px) 100vw, 810px\" \/><\/figure><\/div>\n\n\n\n<p>In the presence of high concentrations of hydrogen ion donors such as hydronium ions, sulfonic acids, and phosphate groups, a &#8220;packed acid mechanism&#8221; has been proposed in which hydrogen ions are conducted through acid-acid interactions. This was believed to occur only when the hydrogen ion donors are close to each other and direct hydrogen bonds are formed, but the present study (Takaya, <strong>Ohashi<\/strong>, et al., 2019) has revealed that even if the distance is great, they can interact indirectly through multiple hydrogen bonds.<\/p>\n\n\n\n<p>The results are expected to contribute to research in various fields, such as the development of the fuel cell materials mentioned above and the possibility of elucidating the acid-base configuration of the hydrogen ion pathway in proteins.<\/p>\n\n\n\n<p class=\"has-text-align-center\">Text by \u6587\u8cac\uff1a\u5927\u5b66\u9662\u751f N.S. Graduate student.<\/p>\n\n\n\n<p class=\"has-text-align-center\">REFERENCE: <a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1016\/j.cplett.2019.136627\" target=\"_blank\">doi.org\/10.1016\/j.cplett.2019.136627<\/a>. Ogawa Takaya, <strong>Hidenori Ohashi<\/strong>\uff08\u5927\u6a4b \u79c0\u4f2f\uff09, Takanori Tamaki, Takeo Yamaguchi, <strong><em>Chemical Physics Letters<\/em><\/strong> (2019)<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u71c3\u6599\u96fb\u6c60\u6750\u6599\u306e\u958b\u767a\u3001\u30bf\u30f3\u30d1\u30af\u8cea\u5185\u306e\u6c34\u7d20\u30a4\u30aa\u30f3\u7d4c\u8def\u306e\u9178\u5869\u57fa\u914d\u7f6e\u3092\u89e3\u660e\u3059\u308b\u53ef\u80fd\u6027\u304c\u3042\u308b\u3002For  development of the fuel cell materials and the possibility of elucidating the acid-base configuration of the hydrogen ion pathway in proteins.<\/p>\n","protected":false},"author":2,"featured_media":1167,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"advanced_seo_description":"","jetpack_seo_html_title":"","jetpack_seo_noindex":false,"jetpack_post_was_ever_published":false,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2}},"categories":[9],"tags":[12],"class_list":["post-1165","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-research","tag-energy-conversion-optimization"],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/i0.wp.com\/tuat-chemphys.net\/wp-content\/uploads\/2021\/01\/1-s2.0-S0009261419305998-gr1_lrg.jpg?fit=2008%2C1510&ssl=1","jetpack_sharing_enabled":true,"jetpack-related-posts":[{"id":6764,"url":"https:\/\/tuat-chemphys.net\/?p=6764","url_meta":{"origin":1165,"position":0},"title":"Seminar 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